滨海基岩矿床安全开采合理隔离层厚度的确定

针对滨海基岩矿床安全开采合理隔离层厚度留设问题，基于材料力学、结构力学等共七种理论计算方法综合确定隔离层厚度，利用点柱式上向水平分层充填法建立三维数值计算模型，通过结合FLAC3D数值模拟软件，分析理论计算结果的合理性，研究不同中段开采充填情况下第四系底部的稳定性特征，最终得出安全开采所需的隔离层厚度必须在12m以上，合理的开采上限必须在-57m以上。通过分析数值计算模型第四系底部的沉降变形，发现第四系底部最大沉降集中于中间采场 ，最大沉降量为13.73mm。研究成果为滨海基岩矿床安全开采，提高资源回采率提供了有益指导。     

耐腐蚀水性铝颜料的制备及表征

为了提高铝颜料在水性涂料中的耐腐蚀性能，以正硅酸乙酯（ TEOS）为前驱物，通过溶胶-凝胶反应在铝颜料表面形成了一层致密的二氧化硅包覆薄膜，通过优化固含量、溶剂种类及 TEOS的用量，提高铝颜料的耐碱性。利用扫描电镜、刮板试验、接触角测试、析氢实验进行表征，结果表明：以无水乙醇为溶剂，铝金属颜料固含量为 10%，升温至 50 ℃后，逐滴加入 6 g TEOS，再升温至 80 ℃，该条件下制备的 SiO₂膜包覆后的铝颜料具有优异的耐碱性，同时表面性能由疏水性转变成亲水性，对铝颜料起到了很好的保护作用。     

Removal of Cu2+ from Water Using Liquid-Liquid Microchannel Extraction

The very good extraction selectivity of Cu²⁺ from water was demonstrated with a new microchannel equipment, by employing di-(2-ethylhexyl)phosphoric acid (D2EHPA) as an extractant and kerosene as a solvent. The effects of different experimental parameters on the extraction efficiency E, the volumetric mass transfer coefficient K_La, and the entrainment were experimentally investigated. The results showed that the extraction efficiency increased with increasing temperature, extractant concentration, phase ratio (organic/aqueous), and pH. The total flow rate, phase ratio, and pH were found to have a great effect on the mass transfer, whereas the temperature and the extractant concentration showed little effect.     

Scheduling distributed flowshops with flexible assembly and set-up time to minimise makespan

The scheduling problems under distributed production or flexible assembly settings have achieved increasing attention in recent years. This paper considers scheduling the integration of these two environments and proposes an original distributed flowshop scheduling problem with flexible assembly and set-up time. Distributed production stage is deployed several homogeneous flowshop factories that process the jobs to be assembled into final products in the flexible assembly stage. The objective is to find a schedule, including a production subschedule for jobs and an assembly subschedule for products, to minimise the makespan. Such a scheduling problem involves four successive decisions: assigning jobs to production factories, sequencing jobs at every factory, designating an assembly machine for each product and sequencing products on each assembly machine. The computational model is first established, and then a constructive heuristic (TPHS) and two hybrid metaheuristics (HVNS and HPSO) are proposed. Numerical experiments have been carried out and results validate the algorithmic feasibility and effectiveness. TPHS can obtain reasonable solutions in a shorter time, while metaheuristics can report better solutions using more yet acceptable time. HPSO is statistically comparable yet less robust compared with HVNS for small-scale instances. For the large-scale case, HPSO outperforms HVNS on both effectiveness and robustness.     

Fabrication of 3D Ni nanosheet array on Crofer22APU interconnect and NiO-YSZ anode support to sinter with small-size Ag nanoparticles for low-temperature sealing SOFCs

A novel low-temperature sealing method was developed to seal solid oxide fuel cells. The 3D Ni nanosheet array was pre-fabricated on faying surfaces of Crofer22APU interconnect and NiO-YSZ anode-support. Then it was covered with Au film without changing its morphology. This special nanostructure improved sintering efficiency between Ag nanoparticles and substrates. A dense joint was obtained at the low-temperature between 250 °C–300 °C. This method effectively avoided the oxidation of interconnect during sealing. When joints were sealed at 300 °C, the shear strength reached 16 MPa. The fracture was mainly located in the central Ag layer, presenting a significant plastic deformation. Due to the effective protection of Ni layer, joints also possessed excellent oxidation resistance in oxidizing atmosphere at 800 °C for 400 h. After high-temperature oxidation, the shear strength was increased to 23 MPa, revealing an increasement of 43.8% compared with the as-sealed condition (16 MPa). This sealing method has great potential in sealing solid oxide fuel cells. It also can be extended to seal other energy-conversion devices.     

Improved reversible dehydrogenation properties of MgH2 by the synergetic effects of graphene oxide-based porous carbon and TiCl3

In this study, we used a combination of graphene oxide-based porous carbon (GC) and titanium chloride (TiCl₃) to improve the reversible dehydrogenation properties of magnesium hydride (MgH₂). Examining the effects of GC and TiCl₃ on the hydrogen storage properties of MgH₂, the study found GC was a useful additive as confinement medium for promoting the reversible dehydrogenation of MgH₂. And TiCl₃ was an efficient catalytic dopant. A series of controlled experiments were carried out to optimize the sample preparation method and the addition amount of GC and TiCl₃. In comparison with the neat MgH₂ system, the MgH₂/GC-TiCl₃ composite prepared under optimized conditions exhibited enhanced dehydrogenation kinetics and lower dehydrogenation temperature. A combination of phase/microstructure/chemical state analyses has been conducted to gain insight into the promoting effects of GC and TiCl₃ on the reversible dehydrogenation of MgH₂. Our study found that GC was a useful scaffold material for tailoring the nanophase structure of MgH₂. And TiCl₃ played an efficient catalytic effect. Therefore, the remarkably improved dehydrogenation properties of MgH₂ should be attributed to the synergetic effects of nanoconfinement and catalysis.     

基于Hausdorff距离的光纤陀螺阈值滤波算法

要实现采矿机组的智能化，必须对采矿机械的位姿进行实时准确地控制。由于开采工作面环境复杂，可选用捷联惯性导航技术来实现对采矿机械的监测。光纤陀螺作为捷联惯导系统的核心元件，其随机噪声制约着惯性导航系统的精度。传统的建模滤波及小波消噪方法由于其自身的局限性，不能保证准确性和去噪效果。所以结合经验模态分解（Empirical Mode Decomposition，EMD），提出了Hausdorff距离（Hausdorff Distance，HD）筛选准则与阈值滤波相结合的去噪算法。该算法以本征模态函数（Intrinsic Mode Function，IMF）与原始信号概率密度函数（Probability Density Function，PDF）的Hausdorff距离为判别依据，对所有IMF进行筛选，之后引入阈值对筛选出的IMF进行滤波处理，最后将其与余项重构。通过试验比较了软硬阈值的滤波效果，确定了该算法采用硬阈值。为验证算法的有效性，将该算法与其他3种方法进行比较，仿真信号与实测陀螺静态漂移数据的试验结果表明了该方法的优越性，能够有效降低陀螺的各项随机误差。     

Improving Properties of Poly(vinylidene fluoride) by Adding Expanded Graphite without Surface Modification via Water‐Assisted Mixing Extrusion

Expanded graphite (EG) is introduced into poly(vinylidene fluoride) (PVDF) by melt mixing extrusion with water injection. The results demonstrate that the unfunctionalized EG in composite prepared with water injection exbibits better dispersion than that in the one prepared without water injection due to the promoting role of water during extrusion. Thus, the PVDF/EG composite with loading of 4 wt% prepared by water‐assisted mixing extrusion (WAME) exhibits electrical conductivity of about three orders of magnitude higher than the neat PVDF and one order of magnitude higher than the one prepared without water injection. Comparing to the neat PVDF, the thermal conductivity of the composites prepared with and without water injection is increased by 101.5% and 75.0%, respectively. The introduced EG leads to increased Young’s modulus and tensile strength especially for the composite prepared by WAME. The present work indicates that WAME can promote the dispersion of EG in PVDF matrix without any extra functionalization.